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Gasoline Distillation Curves

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  • Steve G.
    Expired
    • November 24, 2014
    • 411

    Gasoline Distillation Curves

    I've given this thread the same title as a previous thread on the topic so that anyone searching it will come up with both threads and have an opportunity to hear an alternate view.

    As some will already know, I am not in agreement with the frequent diagnosis of heat soak and percolation as the cause of dripping carbs, hard hot starts and rough idle. I've outlined a few of my reasons below.

    The proponents of this theory have previously posted a fuel distillation chart along with reported temp readings of the fuel system parts as support of their argument.

    My skepticism was not based on the science outlined in the chart thread, but rather on almost 40 years as a Journeyman in the trade and having worked on these cars back in the day. Fuel perc was real, but it's symptoms were very different than what is being described here on the Board. But as I looked at things and remembered my high school physics flaws in the scienc became apparent.

    Further, why do the fuel producers tell us that today's fuels are less likely to have vapour lock and perc issues than they did in years gone by?


    In previous postings it is reported that infrared temp of 150 to 180* were being read on fuel lines and carb bowls. That appears to have come as a surprise to some people, but I know that to be perfectly normal. Always has been. You wouldn't expect anything any different with all the air that comes into the engine compartment having gone through the rad, then is further warmed by the areas of the engine that run above cooling system temps. And gasoline has always had boiling points well below those recorded temp readings. So why doesn't everyone's fuel boil all day long? And why was perc historically only a hot day (not hot engine) event?

    The original thread with the distillation chart surmises that with 40% of the fuel having boiling points below the temp read on the bowl and lines, that fuel must be violently boiling in their respective containers.

    There are two fundamental flaws with that.

    The first is the assumption that the temp of the fuel is the same as the temp measured on the outside of the vessel containing the fuel. All of these theories are based on infrared temp readings of the lines and carb bowl, not of the fuel itself. Given that the source of heat for the fuel is the ambient air and engine components surrounding the containers, that would be like taking the temp of the pot you are boiling water in at a point adjacent to the flame or element. You can put 500* of heat to a pot of water and the water will never exceed 212*. Assuming the temp of the fuel to be the same as it's heating container is more than a stretch, it is illogical.

    The second is that if you understand the reasons the water won't exceed the temp at which it boils, you will know that the fuel can't reach a particular temp until it has boiled off all the elements with boiling points lower than that temp. That's how distillation works and how the curves are established, monitoring the temp as you monitor the decrease in volume. So in order to hit these mid range boiling points you would have had to boil off about 40% of the volume of the fuel you started with. The original thread would seem to suggest that the chart is showing 40% of the fuel is boiling rapidly at the temp in question.

    That's not at all what happens. The way that chart is made is by watching the decrease in the volume of the container as the temp rises. Up to 100*, no change in volume, nothing boiling off yet. As the temp reaches the boiling point of the lowest components it stalls there and does not rise any further no matter how much heat you apply, until it has completely boiled off that element. It is noted how much the volume has decreased at the point that the temp starts to rise again. It levels off again as it reaches the boiling point of the next component. How long it sits at a given temp is determined by how much that particular component makes up of the total.

    So not only is 40% of the fuel not boiling at the same time with a bowl reading of 150*, it can not reach 150* until it has boiled off all the elements with lower boiling points, about 40% of it's total volume.

    So then, when does fuel perc and vapour lock happen. And what is it?

    Historically, those events happened on very hot days. Days when the fuel in the tank approached the lowest of the fuel's boiling points, closing in on 100*. Stuff boils when it's own vapor pressure exceeds the pressure of the elements pushing down on it. This is often atmospheric pressure, but we can raise that boiling point by raising the pressure in the container such as happens in the cooling system under pressure. Similarly, you can lower the boiling point by reducing the pressure above it. This is what happens on the suction side of the fuel pump and why that's where vapour lock occurs. The fuel leaving the tank is almost at the lowest, or beginning, of it's boiling points. The lower pressure on the fuel created by the suction of the fuel pump causes those elements to boil, or vaporize. The pump wants to pull fuel, but because of the low pressure it's creating and the temp of the fuel, all it's getting is the vapour coming off the fuel. It is now vapour locked.

    If the hot fuel makes it past the fuel pump it will continue to pick up heat. It is unlikely to boil in the line from the pump to the carb because it is under pressure, which raises it's boiling point. Once in the bowl it is at atmospheric pressure, or close to it, and it may start to boil, again starting with the components of the fuel with the lowest boiling point. As it boils those off the temp will gradually move up. But as the charts tell us, it has to have lost 40% of it's volume before it could ever hit 150*.

    Which is precisely why it has always been that percing fuel is identified by whispy white vapour coming out the vent, not liquid fuel dropping down the throat when the engine has been shut off and the temp of the engine rises. The liquid fuel level is actually dropping, exiting the bowl via the vent as vapour.

    This is why the fuel industry claims there to be far less of a problem with perc and vapour lock than ever before. Because it's not the mid range of the chart that's important, it's the very beginning that matters. It's the lowest temp at which any of the elements boil that matters. And that starting point is actually significantly higher in the ethanol fuel.

    distillation curves.jpg
    And that is why for over 80 years the automotive repair industry has identified perc by it's white vapour from the vent and attributed dripping liquid fuel down the throat to a high fuel level in the bowl caused by a mechanical malfunction or misadjustment.

    That's my take on it. Due respect to those with differing opinions.

    It's late and I'm out of time. More later.
    Steve
  • Peter S.
    Very Frequent User
    • March 28, 2012
    • 327

    #2
    Re: Gasoline Distillation Curves

    Hi Steve,

    I see some serious fundamental flaws in the principles of distillation/separation. It is in this respect that I have a problem with your opinion, and the consequences that lead to your conclusions. Seader and Henley have a book, Separation Process Principles, that may clarify how separation between liquids and vapors occur and their compositions.

    Peter

    Comment

    • Steve G.
      Expired
      • November 24, 2014
      • 411

      #3
      Re: Gasoline Distillation Curves

      Hi Peter,
      I'm curious what flaws you see in the principles of the distillation process. It's been working fine for years.

      If you mean you see serious flaws in my understanding, let's hear them. The distillation field is not my area of expertise. I researched enough to find out what I needed to know to look at the previous references to the distillation charts and to help me to understand a situation that has been happening for 80 years, but who's symptom's appear to have changed since the invention of the infrared thermometer and the internet.

      It's certainly your prerogative to disagree, but it will contribute a lot more to the discussion if you let us in on what and why.

      Steve

      Comment

      • Peter S.
        Very Frequent User
        • March 28, 2012
        • 327

        #4

        Comment

        • Steve G.
          Expired
          • November 24, 2014
          • 411

          #5
          Re: Gasoline Distillation Curves

          Peter,

          I absolutely and enthusiastically agree with you that the best person to talk about this would be an oil and gas engineer. That was the first thing that came to my mind when I read the original thread that posted the chart I stole and placed on my thread. Have you read that piece?

          The author of the original piece contended that the distillation chart and the infrared thermometer reading were evidence of fuel boiling in the carb. I contend that it is not. I'm not sure how your information fits into an either for or against argument.

          As stated previously, when I read the first thread I was perplexed. What the author contended would mean our fuel would be boiling all the time. I know it doesn't. Underhood temps are always over 150*. And as he points out, 40% of the make up of the gasoline has a boiling points lower than that. In as much as I know the fuel isn't boiling all the time I set out to find out why not.

          In an interesting coincidence, at the time the first thread appeared I had been over at a friends house where he was showing me his still. Apparently you can buy online the components to build your own still. He was in the midst of doing a batch and as he explained what was happening my high school physics came back to me (some of). This was a several hour procedure and he monitored the temp of the mash. The temp would rise as the alcohol boiled off. He stopped the process as the temp of the mash neared 100C, explaining that at that point he would be simply distilling water.

          I guess what I was misunderstanding, from what you are telling me, is that the temp at which his still first started to drip condensate (something was boiling) was not the boiling temp of the alcohol, but rather a boiling point somewhere between the boiling temp of the alcohol and that of all the other liquids in the mash. That may well be, but something was boiling and moving up the tower at a much lower temp than water boils. And it wouldn't get up to the temp the water would boil until it got rid of all that other stuff.

          Now I too am confused at how they could make up the distillation curve. My understanding of why, no matter how much heat you apply, water's temp won't exceed 100C, is because the steam or vapour is carrying heat away with it. So those lower boiling point compound begin to boil and the steam removes heat until they are all gone. Once the boiling stops and no heat is being carried away, the temp starts to rise until it starts to boil again, where it stalls as steam is created again and carries off the heat. Of course with many compounds in very small amounts (which is what I read was the case with gasoline) this process runs together. Is that not the distillation process I was witnessing? And if the bp at a given time is some blended temp, what happens to the water that is combined with the alcohol to create this blended temp? It can't be boiling off, it's not hot enough. Confusing, but interesting.

          However, I don't think any of that alters my supposition. Just as the temp of the mash could not climb up to the boiling point of the water until all this other stuff boiled off ( I watched the temp with my own eyes and with a constant heat it took several hours to reach that), the temp of the fuel in the carb won't rise to those higher boiling points until the compounds with the lower bp's have boiled off. I believe that to be the only part of the distillation process relevant to the question at hand. Is a temp reading of 150* on the exterior of the container evidence that the fuel with characteristics of those shown on the chart will be boiling?

          Steve

          Comment

          • Bruce M.
            Infrequent User
            • January 9, 2014
            • 27

            #6
            Re: Gasoline Distillation Curves

            I hope there's not a test at the end of this thread...

            Comment

            • Peter S.
              Very Frequent User
              • March 28, 2012
              • 327

              #7
              Re: Gasoline Distillation Curves

              ​Answers in red.

              Originally posted by Steve Garner (60691)
              Peter,

              I absolutely and enthusiastically agree with you that the best person to talk about this would be an oil and gas engineer. That was the first thing that came to my mind when I read the original thread that posted the chart I stole and placed on my thread. Have you read that piece?

              I saw it but I did not read through it.


              The author of the original piece contended that the distillation chart and the infrared thermometer reading were evidence of fuel boiling in the carb. I contend that it is not. I'm not sure how your information fits into an either for or against argument.

              I'm not trying to make an argument for either case, because I have minimal knowledge on these old carburetors, their operation and the effects on fuel as it travels to the fuel bowl.


              As stated previously, when I read the first thread I was perplexed. What the author contended would mean our fuel would be boiling all the time. I know it doesn't. Underhood temps are always over 150*. And as he points out, 40% of the make up of the gasoline has a boiling points lower than that. In as much as I know the fuel isn't boiling all the time I set out to find out why not.

              A quick google search can pull up the approximate mass fractions of gasoline (http://bcn.boulder.co.us/basin/water...solinecomp.pdfSOLUTION. Each component's boiling point (and its fraction in the solution) affect the overall solution's boiling point. The point of distillation is to separate based on boiling points, but it is very hard to remove every last bit of each component.

              In an interesting coincidence, at the time the first thread appeared I had been over at a friends house where he was showing me his still. Apparently you can buy online the components to build your own still. He was in the midst of doing a batch and as he explained what was happening my high school physics came back to me (some of). This was a several hour procedure and he monitored the temp of the mash. The temp would rise as the alcohol boiled off. He stopped the process as the temp of the mash neared 100C, explaining that at that point he would be simply distilling water.

              Yes, the temperature of the solution rose because you were removing alcohol, but you were also removing water. You cannot fully remove ethanol from water, you will reach an azeotrope and will be removing a constant mixture of both ethanol and water.

              I guess what I was misunderstanding, from what you are telling me, is that the temp at which his still first started to drip condensate (something was boiling) was not the boiling temp of the alcohol, but rather a boiling point somewhere between the boiling temp of the alcohol and that of all the other liquids in the mash. That may well be, but something was boiling and moving up the tower at a much lower temp than water boils. And it wouldn't get up to the temp the water would boil until it got rid of all that other stuff.

              You are boiling the solution, and the mass fraction of the condensate you are collecting will be high in alcohol, but there will also be water. As I said above, you will not get rid of all that other stuff.

              Now I too am confused at how they could make up the distillation curve. My understanding of why, no matter how much heat you apply, water's temp won't exceed 100C, is because the steam or vapour is carrying heat away with it.


              So those lower boiling point compound begin to boil and the steam removes heat until they are all gone. Once the boiling stops and no heat is being carried away, the temp starts to rise until it starts to boil again, where it stalls as steam is created again and carries off the heat. Of course with many compounds in very small amounts (which is what I read was the case with gasoline) this process runs together. Is that not the distillation process I was witnessing?

              Boiling does not stop, and steam does not remove the heat. Distillation is much more complex than boiling a pot of water.

              And if the bp at a given time is some blended temp, what happens to the water that is combined with the alcohol to create this blended temp? It can't be boiling off, it's not hot enough. Confusing, but interesting.



              However, I don't think any of that alters my supposition. Just as the temp of the mash could not climb up to the boiling point of the water until all this other stuff boiled off ( I watched the temp with my own eyes and with a constant heat it took several hours to reach that), the temp of the fuel in the carb won't rise to those higher boiling points until the compounds with the lower bp's have boiled off.

              This is incorrect.

              I believe that to be the only part of the distillation process relevant to the question at hand. Is a temp reading of 150* on the exterior of the container evidence that the fuel with characteristics of those shown on the chart will be boiling?

              Possibly. This is a question for a knowledgeable oil and gas engineer. It really is not one for us to guess at. At this point, we are just BSing.

              Steve

              Comment

              • Steve G.
                Expired
                • November 24, 2014
                • 411

                #8
                Re: Gasoline Distillation Curves

                Originally posted by Peter Stout (54749)
                ​Answers in red.

                Yes Peter, you're right, this is a far more complex than boiling water. It appears that we are in agreement that you can't identify fuel issues with a distillation chart and an infrared thermometer.

                "Possibly. This is a question for a knowledgeable oil and gas engineer. It really is not one for us to guess at. At this point, we are just BSing. " I'm going to take that as your position being that the original thread and it's contentions are as much BS as you're reading here and your knowledge and skill in your specific field of expertise is of no more value to solving the riddle than the wild a$$ speculations going on the board.

                The objective of this exercise is to improve on the diagnosis of fuel/carb problems, not to reinvent fuel distillation. The popular position on this board is that boiling fuel is most often the problem. I contend it's not. Where do you sit on that?

                So let's forget the science and go with what we know.

                While the composition of the fuel changes very little across the continent, most cars of identical engine configuration don't experience this problem.

                The fuel producers claim vapour lock and volatility issues are less of a problem with today's fuels than they were in the 80's. (read the article linked to in the original thread)

                Fuel perc has been around for ages. It was always identified by white vapour pouring out the vent tubes.

                Fuel perc today is being described as liquid fuel dripping down the throat.

                Engineers of yore were aware of the issue and resolved it by the use of hot idle compensators. The vapour exiting the bowl vent, situated in the throat of the carb, entered the air stream as unmetered fuel and richened the mixture causing rough idle and stalling. Hot idle compensators dealt with that.

                They did not come up with a fix for the drip in the throat caused by perc. Was they because they couldn't figure out how or because it wasn't there?

                Working in the field as a Journeyman almost 40 years ago, fuel dripping down the throats was as common as dirt. We fixed them ALL without changing fuel.

                Edit. Forgot one. Fuel perc went from being a hot day event to a hot engine event.

                All of these things are enough to convince me that the diagnosis of fuel perc that I've seen since I started following the board,100% of the time where the complaint is fuel drip, are suspect. As such the recommended remedy of eliminating heat crucial to the vaporization of the fuel by wiring back heat risers and blocking exhaust crossovers is unnecessary and in my view, counter productive.

                Steve
                Last edited by Steve G.; May 6, 2015, 09:08 AM.

                Comment

                • Peter S.
                  Very Frequent User
                  • March 28, 2012
                  • 327

                  #9
                  Re: Gasoline Distillation Curves

                  Hi Steve,

                  Please do not put words in my mouth - I have no position on the distillation curve and its ability to be applied to this situation. I am also not calling the original thread "BS" because, after perusing it, there is some good, factual information in there.

                  My original intention in commenting in this thread is to correct some egregious interpretation of chemistry taking place. Since i have no knowledge of fuel composition and distillation, nor any real knowledge of the mechanical design of these carburetors, I will have no input in solving fuel drip/percolation issues.

                  Comment

                  • Brad K.
                    Expired
                    • August 31, 1990
                    • 414

                    #10
                    Re: Gasoline Distillation Curves

                    This argument is starting to sound like Leonard and Sheldon on the "Big Bang Theory"......just teasing!

                    Comment

                    • Ed S.
                      Extremely Frequent Poster
                      • August 6, 2014
                      • 1377

                      #11
                      Re: Gasoline Distillation Curves

                      A lot of the discussion thus far is way over my thinning hair but I have to ask. Are we talking about gasoline in the carb bowl (or some of the ingredients that are part of the liquid gasoline solution) that is actually - literally - "boiling" or is what we are witnessing at times is the liquid fuel expanding because it absorbs heat and after it expands its volume exceeds the bowl's capacity - and thus some liquid fuel exits the bowl through the paths it is intended to exit - and down the throat of the carb into the manifold. This is all predicated on the assumption that liquid gasoline expands when it is gets hot. And, I understand that this is a true fact. So, when the car is running the fuel pump is delivering gas to the carb bowl but the gas is also exiting the bowl as it is intended to do. The continuous supply of fresh (cool) gasoline allows the entire system to operate as intended. The gasoline doesn't sit in the bowl long enough to heat and expand. When the car is shut off the flow of gasoline to the bowl stops - what ever gasoline is in the bowl(s) begins to absorb heat from the engine and expands - and...... if it expands too much it has to go somewhere - typically into the carb throats and into the manifold. Thoughs???
                      Ed

                      Comment

                      • Steve G.
                        Expired
                        • November 24, 2014
                        • 411

                        #12
                        Re: Gasoline Distillation Curves

                        Originally posted by Peter Stout (54749)
                        Hi Steve,

                        Please do not put words in my mouth - I have no position on the distillation curve and its ability to be applied to this situation. I am also not calling the original thread "BS" because, after perusing it, there is some good, factual information in there.

                        My original intention in commenting in this thread is to correct some egregious interpretation of chemistry taking place. Since i have no knowledge of fuel composition and distillation, nor any real knowledge of the mechanical design of these carburetors, I will have no input in solving fuel drip/percolation issues.
                        Peter,
                        I'm interested to hear what of the original post is good factual information pertaining to the question it is intending to address. Those are the only ones that interest me.

                        Steve

                        Comment

                        • Steve G.
                          Expired
                          • November 24, 2014
                          • 411

                          #13
                          Re: Gasoline Distillation Curves

                          Originally posted by Ed Szeliga (60294)
                          A lot of the discussion thus far is way over my thinning hair but I have to ask. Are we talking about gasoline in the carb bowl (or some of the ingredients that are part of the liquid gasoline solution) that is actually - literally - "boiling" or is what we are witnessing at times is the liquid fuel expanding because it absorbs heat and after it expands its volume exceeds the bowl's capacity - and thus some liquid fuel exits the bowl through the paths it is intended to exit - and down the throat of the carb into the manifold. This is all predicated on the assumption that liquid gasoline expands when it is gets hot. And, I understand that this is a true fact. So, when the car is running the fuel pump is delivering gas to the carb bowl but the gas is also exiting the bowl as it is intended to do. The continuous supply of fresh (cool) gasoline allows the entire system to operate as intended. The gasoline doesn't sit in the bowl long enough to heat and expand. When the car is shut off the flow of gasoline to the bowl stops - what ever gasoline is in the bowl(s) begins to absorb heat from the engine and expands - and...... if it expands too much it has to go somewhere - typically into the carb throats and into the manifold. Thoughs???
                          Hi Ed,

                          The expansion of the fuel is exactly what I contend happens when things warm up after shut down. Fuel expands, and it always has. The engineers that originally designed carbs all anticipated that. As such they designed there to be more than adequate leeway between the fuel level in the bowl and the spillover point.

                          How much more would the ethanol have to expand than the gasoline it's added to in order to eat up that designed in expansion space, given it makes up only about 10% of the total volume?

                          And again, back in the day when carbs were all we had, that was when a float/needle seat issue would first start to show up. The fuel level in the bowl had crept up enough to where the expansion cushion was not enough. They would drip when they were shut off and sitting.

                          The popular theory on here is that the roiling boil of the fuel is splashing fuel out all over the place, traveling up the vent tube, around a corner for a distance of 2" then spraying out the vent tube. Fuel boiling in the tranfer tubes is exiting as liquid fuel and not vapour coming off the boil.

                          That theory just seems so unlikely to me, particularly in light of my training and experience in the trade.

                          Steve
                          Last edited by Steve G.; May 6, 2015, 11:22 AM.

                          Comment

                          • Peter S.
                            Very Frequent User
                            • March 28, 2012
                            • 327

                            #14

                            Comment

                            • Duke W.
                              Beyond Control Poster
                              • January 1, 1993
                              • 15667

                              #15
                              Re: Gasoline Distillation Curves

                              Yes, I believe ethanol is the primary reason for the lower mid-range position of the distillation curve for modern ethanol-laced gasoline as shown in the Chevron graph.

                              You bring up another good point, Peter, that I'll slightly rephrase. At any given temperature, the greater the mass fraction of fuel components at or above their boiling temperature, the higher the vapor pressure. I'm not sure I so stated in the thread I stated on fuel distillation curves, but perhaps phrasing it this way is easier to understand.

                              And I'll add that the higher the vapor pressure, the greater the mass flow rate of vaporized fuel escaping the liquid and exiting out the bowl vents; and the greater the mass flow rate of fuel vapor, the more likely a hot restart problem due to a high concentration of fuel vapor inside the air cleaner, carburetor, and manifold that may result in a mixture too rich to ignite when cranking is initiated. The A/F rich ignitibililty limit is about 8:1.

                              This does not mean that the fuel in the bowl is at a roiling boil, like a pot of boiling water, however, liquid fuel ejecting from the bowl vents indicates that the fuel in the bowl may be at a roiling bowl, and I consider this the extreme case of percolation. I have not personally observed this phenomemon, but there have been enough reports of it that I consider them credible.

                              Duke
                              Last edited by Duke W.; May 6, 2015, 01:49 PM.

                              Comment

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